γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes

Sean M. Smith, Gia L. Hoang, Rhitankar Pal, Mohammad O.Bani Khaled, Liberty S.W. Pelter, Xiao C Zeng, James M Takacs

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).

Original languageEnglish (US)
Pages (from-to)12180-12182
Number of pages3
JournalChemical Communications
Volume48
Issue number100
DOIs
StatePublished - Dec 28 2012

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Alkenes
Amides
Olefins
Esters

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes. / Smith, Sean M.; Hoang, Gia L.; Pal, Rhitankar; Khaled, Mohammad O.Bani; Pelter, Liberty S.W.; Zeng, Xiao C; Takacs, James M.

In: Chemical Communications, Vol. 48, No. 100, 28.12.2012, p. 12180-12182.

Research output: Contribution to journalArticle

Smith, Sean M. ; Hoang, Gia L. ; Pal, Rhitankar ; Khaled, Mohammad O.Bani ; Pelter, Liberty S.W. ; Zeng, Xiao C ; Takacs, James M. / γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes. In: Chemical Communications. 2012 ; Vol. 48, No. 100. pp. 12180-12182.
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